Size-Dependent Raman Shifts for nanocrystals

Theory of size-dependent resonance Raman intensities in InP nanocrystals

The resonance Raman spectrum of InP nanocrystals is characterized by features ascribable to both longitudinal ~LO! and transverse ~TO! optical modes. The intensity ratio of these modes exhibits a strong size dependence. To calculate the size dependence of the LO and TO Raman cross sections, we combine existing models of Raman scattering, the size dependence of electronic and vibrational structu...

Size dependent carrier recombination in ZnO nanocrystals

Size dependent oxygen buffering capacity of ceria nanocrystals.

The structural, chemical and electronic changes of ceria as a function of decreasing particle size have been studied: at sizes below 5 nm the total amount of reducible oxygen dramatically increases due to superoxide formation on the ceria surface, a result indicative of a size dependent oxygen buffering capacity.

Size-dependent oxygen-related electronic states in silicon nanocrystals

Silicon nanocrystals embedded in SiO2 were isolated with a selective etching procedure, and the isolated nanocrystals’ excitonic emission energy was studied during controlled oxidation. Nanocrystals having initial diameters, d0, of ,2.9–3.4 nm showed a photoluminescence sPLd blueshift upon oxidatively induced size reduction, as expected from models of quantum confinement. Oxidation of smaller S...

A review of size-dependent elasticity for nanostructures

Nanotechnology is one of the pillars of human life in the future. This technology is growing fast and many scientists work in this field. The behavior of materials in nano size varies with that in macro dimension. Therefore scientists have presented various theories for examining the behavior of materials in nano-scale. Accordingly, mechanical behavior of nano-plates, nanotubes nano-beams and n...